First Detection of Methylgermylene in the Gas Phase and Time-Resolved Study of Some of Its Reactions
โ Scribed by Becerra, Rosa; Harrington, Cameron R.; Leigh, William J.; Kefala, Lida A.; Walsh, Robin
- Book ID
- 127091128
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 59 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0276-7333
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
We report rate constants for the reactions of SiMez with SiH,,, MeSiH,, Me2SiH2, Me,SiH, Me,Si and pentamethyldisilane obtained using laser flash photolysis/laser absorption techniques. ArF exciplex laser (193 nm) photolysis of pentamethyldisilane was used to generate SiMe2 radicals in the gas phase
Using a laser flash photolysis/laser probe technique, applied to two different gaseous precursor moleculeS, we report absorption signals in the wavenumber region 17109-17120 cm -~, attributable to previously unobserved rotational transitions in the vibronic spectrum of GeH 2. By time-resolved monito