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Stark effect on the 3455 Å s-triazine triplet state

✍ Scribed by Douwe A. Wiersma

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
328 KB
Volume
16
Category
Article
ISSN
0009-2614

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✦ Synopsis

Stark measurements

on the 25935 cm-' triplet state of s-t&zinc at 4.2'K show that it is electroni~lly dewncrate. The magnitude of the Stark splitting parameter CL = 0.71 debye (splitting is 2crEeff) is about 30% less than that of singlet 'E" at 30014 cm-' (with Eetf = l.SE). I 'ram these results and available Zeeman experiments (Hochstrasser and Lin), it is concluded ihat the triplet state observed is of vibronic 3E" a c' origin. Some ideas concerning the clectric dipole activity of the 3A;' vibronic substate in this manifold are presented.

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