Standard potential of the (Ag+AgCl) electrode in (acetonitrile+water)
✍ Scribed by Carmen A Vega; Maria De Los A Muñiz
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 451 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
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A simple set of electric circuits was used to assemble a pulse generator. With pulse potentials and under galvanostatical control, a clean silver wire was anodized electrochemically for 0.2-0.5 min in 1 .O mol 1-l HCl with a pulse current density of 20 mA cmm2, and the pulse wave parameters of t$t,
The standard potentials of the Ag/AgCl electrode in water-methylcellosolve mixtures have been determined at 25, 30,35,40 and 45°C. The values of E,,,' in each solvent is determined as a function of temperature. The plot of E,,,' against the reciprocal dielectric constant at 25°C indicates the existe