Standard molar enthalpies of formation of nickel(II) β-diketonates and monothio-β-diketonates
✍ Scribed by Manuel A.V. Ribeiro da Silva; Luís M.N.B.F. Santos; Edward Giera
- Book ID
- 108166791
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 231 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0021-9614
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Unsymmetrically substituted//-diketones, RCOCH2COR' (R and R'= aryl) have been synthesized and used to prepare their monothio-fi-diketone derivatives. Because of the similar basicities of the carbonyl oxygen due to the electronic effects of the R and R' groups, a mixture of the monothio-fl-diketones
The standard enthalpies of formation of the following fluorinated b-diketones at T = 298.15 K were determined from their enthalpies of combustion measured using rotating bomb calorimetry.
Vapour pressures as functions of temperature of seven crystalline copper(II) b-diketonates, Cu2, were measured using either the Knudsen mass-loss effusion technique (Oporto apparatus), the simultaneous torsion and mass-loss effusion technique (Utrecht apparatus), or both. From the temperature depen