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Standard Enthalpies of Formation of 2,6-Di-tert-butyl4-methylphenol and 3,5-Di-tert-butylphenol and Their Phenoxy Radicals

✍ Scribed by ManuelRibeiro A. V. da Silva; M.Agostinha R. Matos; Margarida S. Miranda; M.Helena F. A. Sousa; RuiBorges M. dos Santos; Magda M. Bizarro; JoséMartinho A. Simões


Book ID
110350177
Publisher
Springer
Year
2001
Tongue
English
Weight
135 KB
Volume
12
Category
Article
ISSN
1040-0400

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The role of dopant geometry in the photo
✍ Georgii G. Lazarev; Vladimir L. Kuskov; Francisco Lara; Federico García; Anton R 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 550 KB

Radical pairs are formed by photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol (ionol) (1) or 2,6-di-tert-butylphenol (2 ), doped by several different molecules, and investigated by the EPR method. A possible two-hydrogen-atom transfer is discussed as the photochemical act.

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## Abstract Convenient procedures for the synthesis of functionalized mono‐ and bisphosphinates with 2,6‐di‐tert‐butyl‐4‐methylphenol (ionol) fragments, starting from the available 3,5‐di‐tert‐butyl‐4‐benzaldehyde and its derivatives, are proposed, and some properties of the new phosphorus‐substitu