Radical pairs are formed by photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol (ionol) (1) or 2,6-di-tert-butylphenol (2 ), doped by several different molecules, and investigated by the EPR method. A possible two-hydrogen-atom transfer is discussed as the photochemical act.
✦ LIBER ✦
Standard Enthalpies of Formation of 2,6-Di-tert-butyl4-methylphenol and 3,5-Di-tert-butylphenol and Their Phenoxy Radicals
✍ Scribed by ManuelRibeiro A. V. da Silva; M.Agostinha R. Matos; Margarida S. Miranda; M.Helena F. A. Sousa; RuiBorges M. dos Santos; Magda M. Bizarro; JoséMartinho A. Simões
- Book ID
- 110350177
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 135 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1040-0400
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## Abstract Convenient procedures for the synthesis of functionalized mono‐ and bisphosphinates with 2,6‐di‐tert‐butyl‐4‐methylphenol (ionol) fragments, starting from the available 3,5‐di‐tert‐butyl‐4‐benzaldehyde and its derivatives, are proposed, and some properties of the new phosphorus‐substitu