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Standard enthalpies of formation and of sublimation of 2,6-dimethylquinoline and 2,7-dimethylquinoline

✍ Scribed by Manuel A.V. Ribeiro da Silva; M.Agostinha R.M. Matos; Luı́sa M.P.F. Amaral

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
255 KB
Volume
27
Category
Article
ISSN
0021-9614

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✦ Synopsis

The standard (p°= 0.1 MPa) molar enthalpies of formation for crystalline 2,6-dimethylquinoline, 2,6-(CH3)2-C9H5N, and 2,7-dimethylquinoline, 2,7-(CH3)2-C9H5N, at the temperature T=298.15 K, were derived from the standard molar energies of combustion, in oxygen, measured by static-bomb calorimetry. The standard molar enthalpies of sublimation, at T=298.15 K, were measured by microcalorimetry.

DfH°m(cr)/(kJ•mol

-1 ) D g cr H°m/(kJ•mol -1 ) 2,6-dimethylquinoline, 2,6-(CH3)2-C9H5N 36.422.5 84.521.5 2,6-dimethylquinoline, 2,7-(CH3)2-C9H5N 34.322.6 87.521.5

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