## Abstract A quantitative modelling of the disorder phenomena in layered NbS~2~ is presented. The polytypes 2H and 3R are considered and the variations of the intensity profiles for their transformations into each other are calculated in terms of a one-dimensional disorder model.
β¦ LIBER β¦
Stacking disorder in 2H-NbS 2 and its intercalation compounds K x (H 2 O) y NbS 2 II. Stacking disorder in K x (H 2 O) y NbS 2
β Scribed by Katzke, H.
- Book ID
- 120548642
- Publisher
- Oldenbourg Wissenschaftsverlag
- Year
- 2002
- Tongue
- English
- Weight
- 738 KB
- Volume
- 217
- Category
- Article
- ISSN
- 2194-4946
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β¦ Synopsis
Abstract
The intercalation reaction of hydrated K^+^ ions into the layered structure of 2H-NbS~2~ was studied using in situ X-ray diffraction. A structurally complex intercalation mechanism was observed showing several highly one-dimensionally disordered intercalated phases. A quantitative modelling of the disorder in K__~x~(H~2~O)~y~__NbS~2~ is presented allowing a complete understanding of the intercalation mechanism.
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