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Stacking disorder in 2H-NbS 2 and its intercalation compounds K x (H 2 O) y NbS 2 II. Stacking disorder in K x (H 2 O) y NbS 2

✍ Scribed by Katzke, H.


Book ID
120548642
Publisher
Oldenbourg Wissenschaftsverlag
Year
2002
Tongue
English
Weight
738 KB
Volume
217
Category
Article
ISSN
2194-4946

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✦ Synopsis


Abstract

The intercalation reaction of hydrated K^+^ ions into the layered structure of 2H-NbS~2~ was studied using in situ X-ray diffraction. A structurally complex intercalation mechanism was observed showing several highly one-dimensionally disordered intercalated phases. A quantitative modelling of the disorder in K__~x~(H~2~O)~y~__NbS~2~ is presented allowing a complete understanding of the intercalation mechanism.


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Stacking disorder in 2H-NbS 2 and its in
✍ Katzke, H. πŸ“‚ Article πŸ“… 2002 πŸ› Oldenbourg Wissenschaftsverlag 🌐 English βš– 469 KB

## Abstract A quantitative modelling of the disorder phenomena in layered NbS~2~ is presented. The polytypes 2H and 3R are considered and the variations of the intensity profiles for their transformations into each other are calculated in terms of a one-dimensional disorder model.