Stable Monomeric Germanium(II) and Tin(II) Compounds with Terminal Hydrides
β Scribed by Leslie W. Pineda; Vojtech Jancik; Kerstin Starke; Rainer B. Oswald; Herbert W. Roesky
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 130 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract **A happy ending**: The germanium(II) hydride [LGeH], where L=[HC{(CMe)(2,6β__i__Pr~2~C~6~H~3~N)}~2~], reacts with a diazoalkane to form the hydrazone derivative (see picture). The reaction proceeds through the unprecedented endβon nitrogen insertion of the diazo compound.magnified imag
## Abstract New stable amidogermanium(II) and βtin(II) chlorides R~2~Nο£ΏE^14^ο£ΏCl [E^14^ = Ge, R = Et (**1**), E^14^ = Sn, R = Me (**2**)] have been synthesized and their crystal structures have been determined by Xβray diffraction analysis. Both **1** and **2** are dimers formed via the two intermol