Stable ‘gap’ in absorption spectra of solid solutions of organic molecules by laser irradiation
✍ Scribed by B.M. Kharlamov; R.I. Personov; L.A. Bykovskaya
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 167 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0030-4018
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ESR spectra of CsO radical anions were detected for &/MCHX and C,,/MTHF solid solutions which were y-irradiated at 77 K and subsequently annealed at 1 IO-140 K. The g-factors were 2.00 19 and 1.9997 for C,,JMCHX (or CJMCHX-d14) and CJMTHF, respectively. AH,,=O.26 mT was obtained for those solutions
A relationship is obtained between the homogeneous absorption spectrum ofan impurity centre and the hole shape burnt during the strongly inhomogeneously broadened optical transitions of impurities in solids. Model calculations show a strong dependence of the hole shape on the laser frequency and bur