Stable Free Radical Polymerization of Styrene: Controlling the Process with Low Levels of Nitroxide
✍ Scribed by MacLeod, Paula J.; Veregin, Richard P. N.; Odell, Peter G.; Georges, Michael K.
- Book ID
- 127394690
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 52 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The stable nitroxide TEMPO is shown to react with styrene and polystyrene models under conditions typically used for polymerizations. These results show that the nitroxide is not inert at the elevated temperatures necessary to conduct polymerizations. The implications of hydrogen abstraction and ole
## Abstract Bulk radical polymerization of styrene in the presence of nitronyl nitroxides (2‐(4‐substituted phenyl)‐4,4,5,5‐tetramethyl‐4,5‐dihydroimidazolyl‐1‐oxyl 3‐oxide) was studied. All nitronyl nitroxides, like other nitroxyl radicals such as 2,2,6,6‐tetramethylpiperidine 1‐oxyl radical (TEMP