Controlled radical polymerization of styrene with an oxazolidinyl-N-oxyl stable free radical
β Scribed by Yozo Miura; Shiro Mibae; Hiroaki Moto; Norihiro Nakamura; Bunichiro Yamada
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 633 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0170-0839
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract **Summary:** The block copolymers of styrene and ethyl __Ξ±__βcyanocinnamate were prepared in dioxane and xylene with TEMPOβcapped polystyrene (PSTEMPO) as macroinitiator. The copolymerizations were carried out at 125βΒ°C and 135βΒ°C. The reactivity ratios were determined according to Kele
## Abstract The elevated temperatures required for the stable freeβradical polymerization (SFRP) process lead to thermal initiation of styrene via the classic Mayo mechanism. Studies have shown the utility of styrene thermal initiation in controlled autopolymerization processes. In addition, the th