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Stable chlorine intramolecular kinetic isotope effects from the abiotic dehydrochlorination of DDT

โœ Scribed by Christopher M. Reddy; Nicholas J. Drenzek; Timothy I. Eglinton; Linnea J. Heraty; Neil C. Sturchio; Vernon J. Shiner


Publisher
Springer-Verlag
Year
2002
Tongue
English
Weight
463 KB
Volume
9
Category
Article
ISSN
0944-1344

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The kinetics of the gas phase intramolec
โœ Kurt W. Egger ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 654 KB

The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')