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Stable carbonium ions. CII. Bicyclo[3.3.0]-1-octyl cation and its preferential formation from bicyclo[3.2.1]- and -[2.2.2] octyl systems under long-lived ion conditions

โœ Scribed by Olah, George A.; Bollinger, J. Martin.; Kelly, David Patterson.


Book ID
120365580
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
297 KB
Volume
92
Category
Article
ISSN
0002-7863

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In contrast to recent claims by Rhodes and Glidewell, comparison of both ESR and electronic absorption spectra shows that the photoproduct of the recently characterized radical cation of bicyclo[ 3.3.0]octa-2,6-diene-4,8-diyl is identical to the 1,4dihydropentalene radical cation, i.e. a linear conj