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Stable carbocations. CXII. Preferential formation of the bicyclo[3.3.0]-1-octyl cation from bicyclooctyl precursors and its rearrangement to the 2-methylnorbornyl cation

โœ Scribed by Olah, George A.; Leian, Gao


Book ID
119995799
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
475 KB
Volume
93
Category
Article
ISSN
0002-7863

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In contrast to recent claims by Rhodes and Glidewell, comparison of both ESR and electronic absorption spectra shows that the photoproduct of the recently characterized radical cation of bicyclo[ 3.3.0]octa-2,6-diene-4,8-diyl is identical to the 1,4dihydropentalene radical cation, i.e. a linear conj