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Stable allyl-phosphonium and -pyridinium complexes of molybdenum

โœ Scribed by J.A. McCleverty; A.J. Murray


Book ID
108354405
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
259 KB
Volume
149
Category
Article
ISSN
0022-328X

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Allylic coupling between [CpMo(CO)(NO)(q3-allyl)]+ and CpFe(C0)2(q1-allyl) gives equal amounts of two stereoisomers of a 1,5-hexadiene in which the double bonds are complexed to different metals. Removal of the iron moiety yields a single diastereomer of a molybdenum -olefin complex. Investigation