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Stabilized Substituted Ions and Radicals Bearing One Heteroatom (R1R2C-X, R1R2C+X, R1R2CX)

✍ Scribed by A. Schmidt


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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Synthesis of (R, S)-[2,3-13C2]-1-(1β€²-met
✍ Timothy W. Abraham; Edward Leete πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 French βš– 317 KB πŸ‘ 1 views

2-Ethoxy-1-methyl-5-pymlidinone (1) was reacted with ethyl [3,4-'3C2]acetoacetate (2) in the presence of T i c 4 to give ethyl [3,4-13C2]-2-( 1'-methyl-5'oxo-2'-pyrrolidinyl)-3-oxobutanoate (3) in 85% yield. Decarboethoxylation of ethyl [3,4-13C2]-2-( l'-methyl-5'-oxo-2'-pyrrolidiny1)-3-oxobutanoate