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Homoleptic Diphosphacyclobutadiene Complexes [M(η4-P2C2R2)2]x− (M=Fe, Co; x=0, 1)

✍ Scribed by Dr. Robert Wolf; Dr. Andreas W. Ehlers; Dr. Marat M. Khusniyarov; Prof. Dr. František Hartl; Dr. Bas de Bruin; Prof. Dr. Gary J. Long; Prof. Dr. Fernande Grandjean; Dr. Falko M. Schappacher; Prof. Dr. Rainer Pöttgen; Dr. J. Chris Slootweg; Dr. Martin Lutz; Prof. Dr. Anthony L. Spek; Prof. Dr. Koop Lammertsma

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
678 KB
Volume
16
Category
Article
ISSN
0947-6539

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Synthesis and Structure of the First η3-
Synthesis and Structure of the First η3-1,2-Diphosphaallyl Complexes [(η5-C5H5)(CO)2M{η3-RPPC(SiMe3)2}] (M = Mo, R = tBu, Cy; M = W, R = tBu) from [(η5-C5H5)(CO)2M=P=C(SiMe3)2] (M = Mo, W) and Inversely Polarized Phosphaalkenes RP=C(NMe2)2 (R = tBu, Cy)
✍ Lothar Weber; Gabriel Noveski; Ulrich Lassahn; Hans-Georg Stammler; Beate Neuman 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 1 views

## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C