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Stabilization of the P(CF 3 ) 2- and P(C 6 F 5 ) 2- Ions by Coordination to Pentacarbonyl Tungsten: Structures of [18-crown-6-K]P(CF 3 ) 2 , [18-crown-6-K][W{P(CF 3 ) 2 }(CO) 5 ], and [18-crown-6-K][{W(CO) 5 } 2 {μ-P(C 6 F 5 ) 2 }]·THF

✍ Scribed by Hoge, Berthold; Thösen, Christoph; Herrmann, Tobias; Pantenburg, Ingo


Book ID
127382230
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
236 KB
Volume
42
Category
Article
ISSN
0020-1669

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Fluoroborates by Cleavage of Trimethylam
✍ David J. Brauer; Hans Bürger; Regina Hübinger; Gottfried Pawelke 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 183 KB 👁 1 views

Trimethylamine-bis(trifluoromethyl) boranes R(CF 3 ) 2 B ´NMe 3 (R = cis/trans-CF 3 CF=CF (1/2), HCºC (3), H 2 C=CH (4), C 2 H 5 (5), C 6 H 5 CH 2 (6), C 6 F 5 (7), C 6 H 5 (8)) react with NEt 3 ´3 HF depending on the nature of R at 155±200 °C under replacement of the trimethylamine ligand to form