Kinetics of the Reactions of Cl( 2 P 1/2 ) and Cl( 2 P 3/2 ) Atoms with C 2 H 6 , C 2 D 6 , CH 3 F, C 2 H 5 F, and CH 3 CF 3 at 298 K
โ Scribed by Hitsuda, Kanami; Takahashi, Kenshi; Matsumi, Yutaka; Wallington, Timothy J.
- Book ID
- 126829602
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 90 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.
Rate constants for the reactions of atomic oxygen ( 0 3 P ) with C&3F, C&IaCl,C@3Br, 1, l-CzHzFz, and I ,2-C&IzFz have been measured at 307' K using a discharge-flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 1011cm3mole-1s-1)2.63 &0.38,5.22 =tO0.2