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Stabilization of the 8-8-20 Structure-Type in La8−xCaxCu8−yNiyO20

✍ Scribed by G.L. Roberts; R.J. Cava; S.A. Carter; J.J. Krajewski; W.F. Peck; Jr.

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
256 KB
Volume
121
Category
Article
ISSN
0022-4596

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Synthesis and Structure Determination of
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✍ Christine Boyer-Candalen; Alain Meerschaut 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 217 KB

La &10.8 Nb 5 O 20 S 10 was obtained in an attempt to prepare the La homologue of the Sm 3 NbO 4 X 3 derivatives (X ‫؍‬ S, Se). Its structure was solved by X-ray di4raction on a single crystal, in the Immm space group with cell parameters a ‫؍‬ 32.535(8) A > , b ‫؍‬ 12.115(3) A > , and c ‫؍‬ 3.9999(