𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stabilization of Proline Enamine Carboxylates by Amine Bases

✍ Scribed by Dr. Markus B. Schmid; Dr. Kirsten Zeitler; Prof. Dr. Ruth M. Gschwind


Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
954 KB
Volume
18
Category
Article
ISSN
0947-6539

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Local control of peptide conformation: S
✍ Wen-Jin Wu; Daniel P. Raleigh 📂 Article 📅 1998 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 144 KB 👁 1 views

In the native state of proteins there is a marked tendency for an aromatic amino acid to precede a cis proline. There are also significant differences between the three aromatic amino acids with Tyr exhibiting a noticeably higher propensity than Phe or Trp to precede a cis proline residue. In order

Computational Evidence for the Enamine M
✍ Fernando R. Clemente; K. N. Houk 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 336 KB

Theoretical evidence now suggests that the mechanism of the longdebated Hajos-Parrish-Eder-Sauer-Wiechert reaction, the prototype for asymmetric organocatalytic reactions, involves a proline enamine intermediate (center) which undergoes a concerted aldol cyclization with proton transfer. For more de