The thermal stability of a series of organotellurium compounds was determined by thermogravimetric analysis and the stabilizing capacity of the most heat-resistant compounds assessed in natural rubber, polyethylene, and polypropylene by measurement of the oxidative induction time (OIT). The most act
Stabilization of PACREL® by organotellurium compound
✍ Scribed by Jonas Malmström; Lars Engman; Martin Bellander; Karin Jacobsson; Bengt Stenberg; Viveca Lönnberg
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 154 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
✦ Synopsis
The addition of 0.17-0.50% of bis [4-(dimethylamino)phenyl]telluride to the thermoplastic elastomer PACREL significantly improved tensile strength and elongation at break in unaged and oven-aged samples. Chemiluminescence measurements showed that the organotellurium compound considerably prolonged the induction period of thermooxidation of the material and drastically reduced the total luminescence intensity of unaged and aged samples. These results indicate that the improved mechanical properties of diaryl telluride stabilized PACREL can be attributed to the antioxidative (peroxide decomposing, chain breaking) properties of the stabilizer.
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