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Cleavage of Tellurium–Carbon Bonds of Hexavalent Organotellurium Compounds by Potassium Graphite

✍ Scribed by Masataka Miyasato; Mao Minoura; Kin-ya Akiba


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
90 KB
Volume
113
Category
Article
ISSN
0044-8249

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Cleavage of Tellurium–Carbon Bonds of He
✍ Masataka Miyasato; Mao Minoura; Kin-ya Akiba 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 90 KB

The potassium ion intercalated in graphite results in unique reactivity of Ar Te K C (1), formed by cleavage of one of the Te-C(Ar) bonds of Ar Te by KC . Thus, 1 reacted quantitatively with CH I to give Ar TeCH , which was not obtainable from Ar Te Li . The Te-CH bond of Ar TeCH is cleaved in prefe