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Stabilization of aryldiazonium ions by crown ether complexation

โœ Scribed by Bartsch, Richard A.; Chen, Hsien; Haddock, Neil F.; Juri, Pedro N.

Book ID
126136053
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
298 KB
Volume
98
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Photochemical stabilization of aryldiazo
Photochemical stabilization of aryldiazonium salts by crown ether complexation
โœ Richard A. Bartsch; Neil F. Haddock; Douglas W. McCann ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

Crown ether complexes of aryldiazonium ions exhibit markedly enhanced thermal stability relative to the corresponding uncomplexed salts. ' Thus, the thermal decomposition (Schiemann reaction) of P-tert-butylbenzenediazonium fluoroborate in 1,2-dichloroethane is retarded by the presence of 18-crown-6

Complexation of aryldiazonium ions by gl
Complexation of aryldiazonium ions by glymes
โœ Richard A. Bartsch; Pedro N. Juri ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

The complexation of aryldiazonium ions by macrocyclic polyetheIs(crown ethers) has been demonstrated by spectroscopic,1 kinetic,' and calorimetric studies. 3 One to one complexes of aryldiazonium salts and crown ethers have been isolated. 2,4 We now report studies of aryldiazonium ion complexation