Crown ether complexes of aryldiazonium ions exhibit markedly enhanced thermal stability relative to the corresponding uncomplexed salts. ' Thus, the thermal decomposition (Schiemann reaction) of P-tert-butylbenzenediazonium fluoroborate in 1,2-dichloroethane is retarded by the presence of 18-crown-6
β¦ LIBER β¦
Study of substituted aryldiazonium salts and their crown ethers complexes by XPS
β Scribed by Dang-Han Wang; Shi-Hong Liu; Guang-Zhi Xu; Xiang-Yu Sun; Yao-Xing Zhao
- Book ID
- 112058597
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 238 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0256-7660
No coin nor oath required. For personal study only.
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## Abstract A new type of crown ethers containing a diphenyl ether unit has been prepared, the ring size ranging from 12 to 36. ^1^H and ^13^C NMR spectra of both free ligands and their metalβion complexes have been recorded. For 18β and 21βmembered compounds a general downfield shift was observed