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Stability of silicon-based distonic radical cations

✍ Scribed by Kuruvilla Pius; Jayaraman Chandrasekhar


Book ID
103601310
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
228 KB
Volume
87
Category
Article
ISSN
0168-1176

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Formation of Ξ²-distonic oxonium ions: St
✍ Arielle Milliet; Georges Sozzi; Henri E. Audier πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 688 KB

Radical cations derived from the ethers ROCH,CH,OR (R, R = H, CH, , C,HJ were studied, since Bdistonic oxonium ions are often prepared from ionized ethers of glycol. The first step in the fragmentation is a 1,Stransfer of an a-hydrogen to oxygen of a terminal alkoxy group leading to a Wistonic oxoni