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Stability and structure of the 1:2 hydrogen bonded complex of dimethyl ether and HCl

✍ Scribed by Alan Hinchliffe

Publisher
Elsevier Science
Year
1979
Weight
334 KB
Volume
14
Category
Article
ISSN
0378-4487

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✦ Synopsis

SCF-MO calculations for the 1:2 hydrogen-bonded complex Me20..(HC112 predict a structure where both HCl molecules are bonded to the oxygen in a roughly tetrahedral arrangement.

Agreement between calculated and observed energy changes is very satisfactory. Population analysis is used to investigate 'the electron reorganization on complex formation.

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