Stability and Structure of Carbene-Derived Neutral Penta- and Hexacoordinate Silicon Complexes
✍ Scribed by Hollóczki, Oldamur; Nyulászi, László
- Book ID
- 111938538
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 766 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
## Abstract A series of novel hexacoordinate silicon(IV) complexes with two tridentate dianionic S,N,O ligands was synthesized, starting from Si(NCO)~4~. All the compounds synthesized were structurally characterized by single‐crystal X‐ray diffraction and/or solid‐state NMR spectroscopy. In additio
Ab initio and semi-empirical wavefunctions are used to examine the stability of neutral pentacoordinated compounds with the formula HsN-SiXYS, where X and Y are the axial and equatorial ligands, respectively, and both ligands can be H, F, Cl. It is found from both levels of theory that a relatively