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Spotlights on our sister journals: Eur. J. Inorg. Chem. 8/2009

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
566 KB
Volume
2009
Category
Article
ISSN
1434-1948

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โœฆ Synopsis

Half-Bonds" in an Unusual Coordinated S 4 2ร€ Rectangle Don't be square! A rare S 4 2ร€ rectangle bridging two M 2 Cp 2 (m 2 -CH 2 ) 2 (M = Rh, Ir) fragments is found to contain two "halfbonds" with Sร€S distances of 2.70 or 2.90 . Computational studies explore the connection between these "half-bonds" and a Jahn-Teller distortion, as well as possible intermediates that form M 4 S 4 2 + clusters having the S 4 2ร€ rectangle rotated by 908.

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