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Spotlights on our sister journals: Chem. Eur. J. 17/2007

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
163 KB
Volume
2007
Category
Article
ISSN
1434-1948

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โœฆ Synopsis

Remember it well! The achiral sodium salt of poly(4-carboxyphenyl isocyanide) (poly-1-Na) folds into a onehanded helix induced by optically active amines in water, which remains when the amines are completely removed. Further modification of the side groups is possible without loss of memory of macromolecular helicity.

Aptamers

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Spotlights on our sister journals: Chem.
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Holey phosphines! The end capping of triethynylphosphine with bulky groups results in the creation of ligands with a large cavity in which the phosphorus lone-pair electrons are located. The novel coordination properties of these ligands lead to a rate-accelerating effect in the rhodium-catalyzed hy

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Nothing in it! Composite hollow spheres of TiO 2 (shown), BaTiO 3 , and SrTiO 3 with varied crystalline phases and compositions can be synthesized under mild conditions. The sulfonated polystyrene gel templates used ensure that the crystalline hollow spheres grow without damage to their shells.

Spotlights on our sister journals: Chem.
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C H T U N G T R E N N U N G amidines and -formamidinates can be readily prepared by reaction of N-arylformimidates with lithium phosphanides. These compounds were previously inaccessible by methods for the preparation of phosphaamidines and -amidinates. They have the potential to be precursors of P,