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Spontaneous activation of [FeFe]-hydrogenases by an inorganic [2Fe] active site mimic

✍ Scribed by Esselborn, Julian; Lambertz, Camilla; Adamska-Venkatesh, Agnieszka; Simmons, Trevor; Berggren, Gustav; Noth, Jens; Siebel, Judith; Hemschemeier, Anja; Artero, Vincent; Reijerse, Edward; Fontecave, Marc; Lubitz, Wolfgang; Happe, Thomas


Book ID
120939056
Publisher
Nature Publishing Group
Year
2013
Tongue
English
Weight
511 KB
Volume
9
Category
Article
ISSN
1552-4450

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## Abstract The oxidation of the hexacarbonyl(1,3‐dithiolato‐__S__,__S__β€²)diiron complexes **4a**–**4c** with varying amounts of dimethyldioxirane (DMD) was systematically studied. The chemoselectivity of the oxidation products depended upon the substituent R (R=H, Me, 1/2 (CH~2~)~5~). For R=H, fou