## Abstract The oxidation of the hexacarbonyl(1,3βdithiolatoβ__S__,__S__β²)diiron complexes **4a**β**4c** with varying amounts of dimethyldioxirane (DMD) was systematically studied. The chemoselectivity of the oxidation products depended upon the substituent R (R=H, Me, 1/2 (CH~2~)~5~). For R=H, fou
β¦ LIBER β¦
Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the [FeFe]-Hydrogenase Active Site
β Scribed by Olsen, Matthew T.; Bruschi, Maurizio; De Gioia, Luca; Rauchfuss, Thomas B.; Wilson, Scott R.
- Book ID
- 126830290
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 719 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0002-7863
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