Splitless injection of up to hundreds of microliters of liquid samples in capillary GC: Part 1, concept

✍ Scribed by Grob, Konrad ;Brem, Sandra ;Fröhlich, Dieter

• Publisher: John Wiley and Sons
• Year: 1992
• Tongue: English
• Weight: 620 KB
• Volume: 15
• Category: Article
• ISSN: 0935-6304
• DOI: 10.1002/jhrc.1240151006

✦ Synopsis

Abstract

If a sample evaporates by flash vaporization in an empty injector insert, the solute material is well mixed with the expanding solvent vapors and the maximum injection volume is determined by the requirement that no vapors must leave the vaporizing chamber. If evaporation occurs from a surface (e.g., of Tenax packing), however, the solvent evaporates first. The site of evaporation is cooled to the solvent's boiling point, and the cool island formed in the hot injector retains solutes of at least intermediate boiling point (visually observed for perylene). Solvent vapors, free from such solutes, may now expand backwards from the injector insert and leave through the septum purge exit. When solvent evaporation is complete, the site of evaporation warms up, causing the high boiling solutes to evaporate and to be carried into the column by the carrier gas. The technique somewhat resembles PTV injection, but is performed using a classical vaporizing injector.