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Splitless injection of large volumes of aqueous samples - A basic feasibility study

✍ Scribed by Grob, Konrad ;Fröhlich, Dieter

Book ID
102894993
Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
502 KB
Volume
16
Category
Article
ISSN
0935-6304

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✦ Synopsis

Abstract

Experiments with splitless injection of large volumes of aqueous samples by the overflow technique have shown that an organic co‐solvent is necessary to help the packing material (Tenax) retain the liquid. With 25–30% propanol or 15–20% 2‐butoxyethanol, some 800 μl can be injected into a 5 mm i.d. liner. The application of the method is restricted to components eluting above ca 200 °C.

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