Spin—orbit coupling in H3
✍ Scribed by Nis Bjerre; Irene Hazell; D.C. Lorents
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 402 KB
- Volume
- 181
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The fine-structure splittings of the 3d *E" and 2A; states of H, are measured using fast neutral-beam laser spectroscopy. The splittings areanalyzed in terms of the rotational mixing oftbe E" and A; states to yield a value for the spin-orbii coupling constant of H, very close to those of the H and Li atoms. Contrary to previously published values of 40-90 ps, but in agreement with a recent measurement by Helm and co-workers, we find a lifetime of less than 2.1 ps for the long-lived 2p 'A; iy= K=O state. The spin-orbit contribution to predissociation of this state is discussed.
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