𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Spin trapping of radicals in tritiated benzene

✍ Scribed by A. Halpern


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
286 KB
Volume
119
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


Decay or lrilium in labelled benzene containing PBN or ND as spin [raps. produced nitronides. the ESR sprr~ra of which establIshed phrnyl as the sole radical. The yield or Ihe PBN-Ph adducl was compared wilh thal obtained xxhen mualed methanol was dissolved in non-radioockc benzene. These cxpcrimcnrs demonsnxwd that about 75% of rndlcals arise dur 10 internal /I rndiolyns with a G value of abow 0.05, rndwxing a Idch of any slgnificnm LET eKtzc1 z, compared with hard y Klys


πŸ“œ SIMILAR VOLUMES


Spin trapping chemistry of acyl radicals
✍ Edward G. Janzen; Edward R. Davis; Coit M. DuBose πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 664 KB

## Abstract The EPR spectra of a variety of different acyl radical adducts of PBN (__C__‐phenyl __N‐tert__‐butyl nitrone) and MNP (2‐methyl‐2‐nitrosopropane) were measured and their hyperfine splitting constants determined. Included are benzoyl, acetyl and other alkylacyl, alkoxyacyl, aminoacyl and

Spin Trapping Chemistry of Iminyl Free R
✍ Edward G. Janzen; Dale E. Nutter πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 408 KB

The iminyl radicals formed from hydrogen atom abstraction between tert-butoxyl radicals and benzylidene-Nalkyl-or N-arylamines were trapped by 2-methyl-2-nitrosopropane and investigated by EPR spectroscopy. The compounds investigated were benzylidene N-methyl, ethyl, 1-propyl, 1-butyl, 2-methylpropy

Synthesis of Spin Trapping Reagents for
✍ Kosei Shioji πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons βš– 11 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Spin trapping of sterically unhindered p
✍ Ladislav Omelka; Jana KovÑčovΓ‘ πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 437 KB

## Abstract Unhindered phenols were oxidized with PbO~2~ in the presence of nitrosobonzene and nitrosodurene. The phenoxyl radicals generated are trapped in their resonance form as __ortho__‐carbon‐centred radicals. Depending on the substitution of the spin trap, two types of aminoxyl radicals are