Spin trapping of radicals in tritiated benzene
β Scribed by A. Halpern
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 286 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Decay or lrilium in labelled benzene containing PBN or ND as spin [raps. produced nitronides. the ESR sprr~ra of which establIshed phrnyl as the sole radical. The yield or Ihe PBN-Ph adducl was compared wilh thal obtained xxhen mualed methanol was dissolved in non-radioockc benzene. These cxpcrimcnrs demonsnxwd that about 75% of rndlcals arise dur 10 internal /I rndiolyns with a G value of abow 0.05, rndwxing a Idch of any slgnificnm LET eKtzc1 z, compared with hard y Klys
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The iminyl radicals formed from hydrogen atom abstraction between tert-butoxyl radicals and benzylidene-Nalkyl-or N-arylamines were trapped by 2-methyl-2-nitrosopropane and investigated by EPR spectroscopy. The compounds investigated were benzylidene N-methyl, ethyl, 1-propyl, 1-butyl, 2-methylpropy
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## Abstract Unhindered phenols were oxidized with PbO~2~ in the presence of nitrosobonzene and nitrosodurene. The phenoxyl radicals generated are trapped in their resonance form as __ortho__βcarbonβcentred radicals. Depending on the substitution of the spin trap, two types of aminoxyl radicals are