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Spin transition centres linked by the nitroprusside ion. The cooperative transition in bis(2,6-bis(pyrazol-3-yl)pyridine)iron(ii) nitroprusside

✍ Scribed by Sugiyarto, Kristian H.; McHale, Wendy-Anne; Craig, Donald C.; Rae, A. David; Scudder, Marcia L.; Goodwin, Harold A.


Book ID
118173896
Publisher
Royal Society of Chemistry
Year
2003
Tongue
English
Weight
408 KB
Volume
12
Category
Article
ISSN
1477-9226

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πŸ“œ SIMILAR VOLUMES


Lattice trapping of metastable quintet s
✍ Harold A. Goodwin; Kristian H. Sugiyarto πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 393 KB

The 'Tz% 'A, spin transition in [ Fe( bpp),][ BF412 (bpp= 2,6-bis( pyrazol-3-yl)pyridine) is abrupt and complete and shows hysteresis with the transition temperatures r,r = 173 K and T,t = 183 K. Rapid cooling of the sample causes the freezing-in of metastable quintet state species at low temperatur