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Anomalous Spin Transition Observed in Bis(2,6-bis(pyrazol-3-yl)pyridine)iron(II) Thiocyanate Dihydrate

✍ Scribed by A. Bhattacharjee; V. Ksenofontov; K.H. Sugiyarto; H.A. Goodwin; P. Gütlich


Book ID
101416659
Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
392 KB
Volume
13
Category
Article
ISSN
1616-301X

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Lattice trapping of metastable quintet s
✍ Harold A. Goodwin; Kristian H. Sugiyarto 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 393 KB

The 'Tz% 'A, spin transition in [ Fe( bpp),][ BF412 (bpp= 2,6-bis( pyrazol-3-yl)pyridine) is abrupt and complete and shows hysteresis with the transition temperatures r,r = 173 K and T,t = 183 K. Rapid cooling of the sample causes the freezing-in of metastable quintet state species at low temperatur