In egg lecithin-water lamellar phases, spin-labeled stearic acid gives two superimposed ESR spectra which are only well resolved when the temperature is greater than 30 degrees C. These two spectral components are attributed to the dissociated and non-dissociated forms of the fatty acid carboxylic g
Spin-labeled polyuridylic acid. Formation of an intermediate structure
✍ Scribed by Yu-Ching E. Pan; Albert M. Bobst
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1974
- Tongue
- English
- Weight
- 293 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0006-3525
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✦ Synopsis
Abstract
Temperature‐dependent conformational transitions of spin‐labeled poly(U) at low temperature in spermidine and cesium chloride buffer have been measured by electron spin resonance spectroscopy. The Arrhenius plot shows the existence of the order‐disorder transition at a temperature close to that obtained from absorbance temperature profiles. However, in addition the formation of an intermediate state is observed during the melting of the ordered poly(U) to its random coil.
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The ESR spectra of a spin-labelled 9:1 copolymer of 1-(2-sulphoethyl)-4-vinylpyridinium betaine and 4-vinylpyridine hydrochloride (a zwitterionic polymer) and spin-labelled poly(4-vinylpyridine) hydrochloride (a polyelectrolyte) have been measured in water as a function of the NaC1 concentration. It