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Spin Crossover in a Tetranuclear Cr(III)−Fe(III)3 Complex

✍ Scribed by Herchel, Radovan; Boča, Roman; Gembický, Milan; Kožís̃ek, Jozef; Renz, Franz

Book ID
111889974
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
75 KB
Volume
43
Category
Article
ISSN
0020-1669

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✍ Paulo N. Martinho; Charles J. Harding; Helge Müller-Bunz; Martin Albrecht; Grace 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 357 KB

## Abstract Thermal spin crossover (SCO) was induced in a high‐spin Fe^III^ complex by alkylation of the polyamino ligand backbone. The SCO profile was responsive to chain length with partial crossover observed with C~6~ alkylation and full transition upon lengthening to C~12~. No crossover was obs