## Abstract Irradiation (λ > 370 nm) of 4,4‐dimethoxy‐2,5‐cyclohexadienone (**1 a**) in benzene affords mainly the ketene acetal **4 a**, which then undergoes further rearrangement. The carbomethoxycyclopentenones **6** and **7** were isolated in modest yields (10–15°). It is conceivable that the l
✦ LIBER ✦
Spektroskopische Identifizierung polymethylsubstituierter 2, 4-Cyclohexadienone
✍ Scribed by Prof. Dr. Gerhard Quinkert; Dr. Gerd Dürner; Dr. Erna Kleiner; Erhard Haupt; Prof. Dr. Dieter Leibfritz
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 206 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The photolysis of a heptane solution of 2,6‐di‐__tert__‐butyl‐4‐__tert__‐butylperoxy‐4‐methyl‐ 2,5‐cyclohexadienone (1) with light of 360–480 nm in the presence of 2,6‐di‐__tert__‐butyl‐4‐methylphenol or 2,4,6‐tri‐__tert__‐butylphenol gives rise to their corresponding phenoxyls in a rea