Spectroscopic Identification of Polymethyl-Substituted 2,4-Cyclohexadienones
✍ Scribed by Prof. Dr. Gerhard Quinkert; Dr. Gerd Dürner; Dr. Erna Kleiner; Dipl.-Chem. Erhard Haupt; Prof. Dr. Dieter Leibfritz
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 240 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Irradiation (λ > 370 nm) of 4,4‐dimethoxy‐2,5‐cyclohexadienone (**1 a**) in benzene affords mainly the ketene acetal **4 a**, which then undergoes further rearrangement. The carbomethoxycyclopentenones **6** and **7** were isolated in modest yields (10–15°). It is conceivable that the l
## Abstract __Substituted 2‐tropolone natural products are found in plants and fungi. Their biosynthesis is thought to occur by ring expansion from a cyclohexadienone precursor, but this reaction has not previously been demonstrated experimentally. Treatment of 6‐hydroxy‐6‐hydroxymethylcyclohexa‐2,
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