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Spectroscopy of MnF: Rotational analysis of the d5Π-a5Σ+ (0,0) band

✍ Scribed by Olli Launila; Benoit Simard


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
681 KB
Volume
154
Category
Article
ISSN
0022-2852

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Spectroscopy of MnF: Rotational Analysis
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A band system of the \(\mathrm{MnF}\) molecule at \(832 \mathrm{~nm}\) representing the \(b^{5} \Pi_{i}-a^{5} \Sigma^{+}\)transition has been studied at low temperature by laser-induced fluorescence in a supersonic jet and at high temperature in a hollow cathode discharge by Fourier transform spectr

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The 0-0 band of the A ˜2P-X ˜2S / transition of CaCCH has been rotationally analyzed through CW dye laser excitation. A total of 440 rotational lines of this band were recorded with high precision, 0.0035 cm 01 . A least-squares fit of the line positions using a standard 2 P-2 S / model provides acc