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Spectroscopy of Hydrothermal Reactions 15. The pH and Counterion Effects on the Decarboxylation Kinetics of the Malonate System

โœ Scribed by Gunawardena, N. R.; Brill, T. B.


Book ID
126159523
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
72 KB
Volume
105
Category
Article
ISSN
1089-5639

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Spectroscopy of hydrothermal reactions,
โœ Jun Li; Thomas B. Brill ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 149 KB

## Abstract The kinetics of decarboxylation of six ฮฑโ€amino acids (glycine, alanine, aminobutyric acid, valine, leucine, and isoleucine) and ฮฒโ€aminobutyric acid were studied in aqueous solution at 310โ€“330ห†C and 275 bar over the pH~25~ range 1.5โ€“8.5 by using an in situ FTโ€IR spectroscopy flow reactor