Spectroscopic, Thermal and Structural Studies of Cocrystals of 2,2′-Diamino-4,4′-bis(1,3-thiazole) with 2,5-Bis(4-pyridyl)-3,4-Diaza-2,4-Hexadiene and 1,2-Bis(4-pyridyl)Ethylenediamine
✍ Scribed by Jafar Abedini; Robabeh Safiei; Zohreh Rashidi Ranjbar; Ali Morsali
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 498 KB
- Volume
- 40
- Category
- Article
- ISSN
- 1572-8854
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📜 SIMILAR VOLUMES
The two pyridine rings in the title compound, C 12 H 10 N 6 , form dihedral angles of 35.7 (2) and 16.8 (2) with the central triazole ring. The molecules exist as centrosymmetrically related dimers and form a three-dimensional network through intermolecular NÐHÁ Á ÁN hydrogen bonds.
In the title compound, [Cu(C 16 H 16 N 4 ) 2 ](ClO 4 ) 2 , the Cu II atom lies on an inversion centre and has a distorted square-planar geometry. In each ligand, the dihedral angle between the triazole and pyridine rings is 9.1 (3) , and that between the triazole and benzene rings is 85.01 ( 14) .