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Spectroscopic studies on the electron donor—acceptor interaction between 1-propanamine-3-triethoxysilyl and π-acceptors

✍ Scribed by Wasfy N. Wassef; Nadia M. Ghobrial; Samia M. Agami

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
319 KB
Volume
47
Category
Article
ISSN
1386-1425

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✦ Synopsis

The spectrophotometric properties of the title interaction have been studied in methylene chloride. 2:l charge-transfer (CT) complexes were formed between the acceptors and the donor, except with 2.3dichloro-5,6-dicyanobenzoquinone (DDQ) a 4:l complex was formed between the acceptor and the donor. The UV-vis. and IR spectral data for the CT complexes and the solvent effect on the electronic transition of the CX have been presented and discussed. The ionization potential of the donor was determined.

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