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Spectroscopic studies of the molecular imprinting self-assembly process

✍ Scribed by Johan Svenson; Håkan S. Andersson; Sergey A. Piletsky; Ian A. Nicholls

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
54 KB
Volume
11
Category
Article
ISSN
0952-3499

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✦ Synopsis

A method for the rapid estimation of the extent of complex formation in molecular imprinting prepolymerization mixtures is described. By the use of a UV spectroscopy titration procedure, apparent binding constants for such self-assembly processes have been obtained. This method was used for comparison of the interactions between a dipeptide template (N-acetyl-L-phenylalaninyl-L-tryptophanyl methyl ester) and the functional monomer methacrylic acid, and the monomer analogues acetic acid and trifluoroacetic acid. The importance of template-monomer association during the molecular imprinting prepolymerization phase is discussed with respect to the systems studied.

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