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Spectroscopic studies of ionic solvation. XVIII. Solvation of the lithium ion in acetone and acetone-nitromethane mixtures

✍ Scribed by Robert G. Baum; Alexander I. Popov

Book ID
104860697
Publisher
Springer US
Year
1975
Tongue
English
Weight
618 KB
Volume
4
Category
Article
ISSN
0095-9782

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✍ Martyn C.R. Symons; Graham Eaton πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 157 KB

Studies of the C=O suetchmg mode of acetone in fluid aqueous solutions suggest that water forms two hydrogen bonds to each oxygen atom. In marked contrast, acetone in frozen solutions is endathrated by water, there being no hydrogen bonds to the carboxy oxygen. Reasons for this contxast are discusse