Spectroscopic properties of methyl thiolfluoroformate, FC(O)SCH3
✍ Scribed by C. O. Della Védova
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 438 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0377-0486
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📜 SIMILAR VOLUMES
## Abstract Matrix‐isolation experiments have afforded the means of preparing the hitherto unknown sulfur(II) fluoride, methanesulfenyl fluoride, CH~3~SF. Broadband UV‐visible irradiation of methyl thiofluoroformate, FC(O)SCH~3~, isolated in a solid Ar matrix results, first, in photoisomerization o
Starting from trimethylsilyl bromide and fluorocarbonylsulphenyl chloride, the compound fluorocarbonylsulphenyl bromide, FC(O)SBr, has been prepared. The IR, Raman, UV, mass, I9F-and "C-NMR spectra have been obtained and interpreted. The vibrational data point to the existence of planar trans and ci