The photophysical behavior of biphenylene has been investigated employing picosecond time-resolved absorption measurements over the range 400-760 nm. The temporal behavior of the different absorption maxima suggest that the transient absorption results from two different configurations of biphenylen
Spectroscopic measurements of biphenylene singlet states
β Scribed by Horn-Bond Lin; Michael Topp
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 529 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
We report the observation of fhrorescexe from higher singIet levels of biphenyIene. The moIecuIe was excited by either txo-or three-photon absorption and the resulting fluorescence to the ground state was observed in a broad band centered near 265 nm_ We have measured the decay time of the lowest exited singlet state to be 240 f 20 ps in he.xane at 300 I(.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Three newly found vibrational levels at energies Te(v) = 45127.88(3), 51900.40(4), and 52604.95(3) cm-1 allow the first application of resonance-enhanced multiphoton ionization for detecting the SO radical in its low-energy singlet states, a1Delta and b1Sigma+. The analysis of the spectra is based o